I don't track pH as there are better ways..namely, tracking alkalinity. I recommend the same for others unless they are doing something relatively risky like running a CO2 reactor. With rare exceptions, pH should be pretty superfluous for anyone tracking and maintaining alkalinity. If you're one of the rare souls with high CO2 levels in the house....well, at least you only have to figure it out once.
To the OP, how do you mean your CO2 scrubber doesn't work anymore? Can you elaborate?
If you
follow the chemistry there's no chance of creating a pH issue anyway...but if you already have issues (anything), they'd be better off being addressed before doing anything like
starting a new dosing regimen with vinegar, or anything else.

I'm also dosing only 30 mL per 5 gallons of ATO into a 100 gallon system that has almost no bio-load other than being packed with SPS, so I don't know if that counts as very much for carbon dosing. It still does the trick for the mineral boost!

I think if I were carbon dosing I would still use this method though.
And FWIW, if you're already dosing two-part (getting back to the OP's situation) you should already be getting a little pH boost from the washing soda as its carbonates "soak up" some of the excess CO2 in the water. Have you thought about placing your alkalinity dose so it's hitting the tank right through this low pH swing?
FWIW, even dosing kalk+vinegar with two-part, I ended up switching to plain baking soda to keep the pH from spiking (I was dosing large quantities so it was getting hard to manage....not a problem at all starting out.)....a slight dip is preferable to a slight spike for me, if I have to choose. If you are solely going mostly for the pH boost you would want to leave the vinegar aside though, you're right.
And BTW, if anyone isn't familiar with the Tunze 5074 kalk dispenser (especially if you're already running an Aqualifter, which works great with it) you should check it out. Much better way of dosing kalk (with and without vinegar)...eliminates almost every downside/risk of kalk and I think it makes it even simpler than manual methods.
-Matt