I did the same as you, testing through a window 1st. For me, it made a difference of about .2 or so. I still couldn't justify drilling a hole through the exterior wall so I instead went through the wall but up into the attic. From there I ran the line out of the soffit. Figured it's easier to patch drywall than the brick outside. Have a total of about 30 feet of hose ran and as you walk up to the house you can hear it sucking. Fun to watch people trying to figure out what that noise is when they walk up to the house.
Once you have enough load to justify dosing, you'll be able to have that ph bump as well. I recently switched to Randy's newer formula to give an extra ph bump. Between the fresh air in the skimmer and the dosing regimen I'm currently on, my daytime ph high went from around 8 to now running at about 8.4. For some reference my system is around 300 gallons, currently dosing 85ml/day, and currently using a reef octopus classic 160int with the aquatrance 2000s pump (specs says it pulls 720 lph/25 scfh of air). I'm about ready to start plumbing my reef octopus sro5000xp into the system that uses a dc5500 pump (2,000 lph/ 70 scfh). My own curiosity has me wondering if the extra air from the bigger skimmer will have much more of an impact to my system.