Randy’s carbon dosing experience question

I found some old posts of mine on another site that more clearly relate what happened at very high doses than i can remember now:

OK, I've been experimenting with upping and upping the vinegar dose for my tank. Hoping to stop any green algae on the glass and kill off some macroalgae and maybe bryopsis (which has not worked).

I've been adding more and more vinegar and less and less vodka.

Well, at the recent limit of 410 mL of lime-saturated vinegar, the tank really was noticeably poorer.

Most particularly, the RBTAs browned up (still orange, but darker and the white parts are now brown) and they expanded less and less, and the H. crispa also expanded less. Some soft corals were also shrunken.

Cyano also started to grow faster again.

Also, the green algae on the glass seemed to grow faster! Bryopsis is also out of control, although that may not be related.

So I’ve decided to cut way back and try 150 ml of lime-saturated vinegar with no vodka for a bit and see if things go back to normal.

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FWIW, I was expecting to start to see bacteria, but I haven't seen any in the display tank. I also never saw anything turn pale.

It is clear to me that the zoox in my RBTA's can clearly consume the acetate and so they increased in population. Maybe that isn't true of SPS corals, and that is why they turn pale and not brown (I don't currently have any SPS). My LPS seem largely unchanged.

The dose of 410 mL was about 2 ml per gallon per day. Maybe a bit less.

I don't generally track calcium and alkalinity, since it never varies much from acceptable ranges, but I do not think there is much rise. The amount dosed is equivalent to about 2 gallons of limewater per day, and that is well within the amounts I usually dose. This is a low evaporation time of the year for me, and so the top off limewater is slow.
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Yes, it was a fairly gradual rise, made in jumps, but still over a long time (months).

Yes, I'm fairly sure the brown is zoox levels being higher. I expect they will drop back.

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OK, I've slowly backed all the way down to about 44 ml per day, spread over the daylight hours. Things look much better. I did not realize how cloudy the water had gotten, presumably with suspended bacteria.

The RBTA's are largely back to normal, but I did loose one that I'd had for only about a month (not sure if that is related or not, but it could well be). The H. crispa seems back to normal.

The cyano is largely gone.

The green algae on the glass is growing more slowly again.

The soft corals are expanding fully again.

All in all, looking good, and I may add some new livestock (anemones and/or fish) in the next few days.
 
Thanks, Randy. I really appreciate it. You’re the best!
 
I’m not sure why my nutrients never bottomed out that I noticed, but the fact that I let detritus collect as a deep mud in my sump may have played a role. I expected them to go lower

I have a question ! Can someone please help me…My phos is about .3 and nitrates are 25. The po4 drops over 24 hrs from about .3 to .1 but don’t see drop in nitrates really more just staying at 25ppm. I just started dosing neophos Po4 to the tank at 5ml daily and it brings my Po4 to about .3 and by next day it’s .1 and. Nitrates stay the same at 25. Any suggestions? I’m carbon dosing vinegar and have been for about 3 months I’m up to 70ml vinegar a day in 120 gallon system with tons of rock and sand so actually only has 82 actual gallons in system. Should I stop raising my carbon dosing or keep raising the carbon dosing until I see nitrates start to fall and just keep dosing po4 to keep the bacteria fed with po4 as it consumes nitrate? I should mention my tank is heavily stocked, very heavily stocked around 22 fish with a 3ft zebra moray eel. I have not had too big of drops in PH with dosing so much carbon because I dose over 24 hrs every other hr and I dose 5 minutes after dosing soda ash to help keep the Ph stable. I don’t think I can keep raising the vinegar dosing past 70ml a day though because I will start to see a drop in PH. I have also noticed that the first day of raising my carbon dosing weekly I would notice about a .1 ph drop over the first day until my system caught back up. Should I just continue to raise vinegar dosing and keep an eye on ph until nitrates start to drop ? Should I dose more phosphates until I’m at a 1/16 ration to nitrates ? But 25 nitrates would mean I would have to have 1.5 PHOS ? Some help here would be greatly appreciated from someone with knowledge behind carbon dosing. How much is too much carbon dosing? Will I ever see my nitrates start to drop?
 
My phos is about .3 and nitrates are 25. The po4 drops over 24 hrs from about .3 to .1 but don’t see drop in nitrates really more just staying at 25ppm.

So let's back up.

That drop is when doing what?

no reasonable amount of carbon dosing will drop 0.3 ppm phosphate in 24 h.

0.3 ppm is also plenty to allow nitrate lowering. So is 0.1 ppm. I don't think any organisms will be phosphate limited at 0.1 ppm phosphate.
 
So let's back up.

That drop is when doing what?

no reasonable amount of carbon dosing will drop 0.3 ppm phosphate in 24 h.

0.3 ppm is also plenty to allow nitrate lowering. So is 0.1 ppm. I don't think any organisms will be phosphate limited at 0.1 ppm phosphate.
Sorry I probably should’ve explained myself better let me back up here and help u better understand. So when I started dosing carbon (vinegar) 3 months ago I took my GFO reactor offline because my phosphates had been zero’d out for a while and I am still learning here so I made the mistake of thinking zero phosphate was good but my nitrates the only way I could keep them at 25 was thru water changes. As I started getting more coral I started dosing calcium, magnesium and Alk (soda ash) seperately on a doser. I soon learned that water changes were getting harder because I then needed to match all water parameters including the aforementioned and salinity and temp. So I started learning about carbon dosing and started very slow in an attempt to lower nitrates and then as I learned you need some phosphate in the system to lower nitrate. I read at a 1/16 ratio so over the three month I started feeding just pellets as they have the highest phosphate content and it helped bring my phosphate from zero to about .2 but if I went one day without feeding pellets and chose frozen instead my phosphates would drop from .2 to about .06 - .1
So over the last week I have been dosing Neophos to bring up my phosphates in hope it would drop my nitrates but haven’t saw any difference in nitrates yet. I dose 5 ml Neophos at lights on and it’ll bring my phosphate up to .3 with feeding pellets. Then 24 hrs later I will measure phos again at .1 -.15 nitrates still at 25ppm. I should mention I do see a slight drop in PH of about .1 when I dose Neophos at 5ml but it comes back up over next hr.
 
So let's back up.

That drop is when doing what?

no reasonable amount of carbon dosing will drop 0.3 ppm phosphate in 24 h.

0.3 ppm is also plenty to allow nitrate lowering. So is 0.1 ppm. I don't think any organisms will be phosphate limited at 0.1 ppm phosphate.
Should I Continue to up my vinegar dosing and at what point is too much? In 82 total gallon of water. I’m dosing 70ml daily. Should I stop dosing the Neophos after reading my last reply? I know your busy man and I really would appreciate some input on this if im ok to continue going up on the amount or just go back to doing water changes and forget the whole thing?

Here is my dosing schedule below i dose carbon 24 hrs around the clock because im dosing so much I don’t want to affect PH dosing such high amount of carbon during just lights on hrs.

Dosing schedule
10pm 2ML AlK, 5ml vinegar
11pm 13ML Mag
12am 2ml ALK, 5ml vinegar
1am
2am 2ML ALK, 5ml vinegar
3am
4am 2ML ALK, 5ml vinegar
5am
6am 2ML ALK, 5ml vinegar
7am
8am 2ML AlK, 5ml vinegar
9am 2ml Cal
10 am 2ML AlK, 5ml vinegar
11am 7ml Cal. ** LIGHTS COME ON***
12pm 6ML ALK, 7ml Vinegar
1pm 7ml Cal
2pm 6ml ALK, 7ml vinegar
3pm 7ml Cal
4pm 6ml ALK, 7ml vinegar
5pm 7ml Cal
6pm 6ml AlK, 7ml vinegar
7pm 7ml Cal
8pm 7ml ALK, 7ml vinegar
9pm 7ml Cal ***LIGHTS TURN OFF***

I dose manually 5 ml NeoPhos at 11am

And Twice a week I dose Reef Trace and Reef Plus by Seachem. Per instructions
 
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