Dropped from 9 to 7.26 overnight. I just tested alk and it was 130ppm
So what do I win for having the tank that won't hold alkalinity? Nothing but more headaches. I am going to test Magnesium and Calcium in a few minutes. Fun Fun Fun
Your problem is the massively high calcium level causing precipitation. Your water is far too saturated with calcium for your magnesium to prevent from precipitating. Since calcium can only precipitate WITH carbonate, your alkalinity is going to drop (exactly what you are seeing...). It will CONTINUE to drop until your calcium comes down to a level where your water isn't so saturated and magnesium can do it's job of preventing precipitation. For seawater to be stable - Calcium, Alkalinity, and Magnesium need to be balanced, or close to it since seawater is super-saturated with calcium and (bi)carbonate ions and the magnesium ions prevent it from precipitating out. When they are out of balance, they naturally tend back toward balance by precipitating.
Here is how to fix this (it takes a bit of time):
1. Get your magnesium where it needs to be - above 1350ppm. It takes a TON of additive - you can dose 150ppm per day worth of magnesium. The higher magnesium goes, the less precipitation there will be which will make this process go slower - a GOOD thing.
2. STOP DOSING ANY CALCIUM
3. Measure your Alkalinity daily and dose ONLY enough alkalinity to return it to NSW levels. You don't have to dose and can instead just do water changes - this will do the same thing but ALSO add calcium and make the process slower. You could also do a 100% water change and be done with it permanently.
Once your tank is balanced - stop dosing alltogether and just do water changes to keep your parameters stable. Don't dose unless you know exactly what it is doing to your water. Never chase numbers -
especially pH. pH is the worst possible parameter to chase. Seawater is stable, but also extremely complex - there is a lot of chemistry going on in our water that most of us don't fully understand. Unless you understand what is happening chemically to your water when you dose, you should not be doing it. You need to know how to undo anything you do to your tank.