I personnel find that a simple method has worked best for me. Mostly because there are far fewer chances for a mistake or other kind of problem so I have eliminated them altogether.
I use Kalk, this has to be the simplest method of maintaining ALK/Cal levels. Also my system for adding top off and Kalk is as simple as possible. The entire system is a 32g Brute a BRS 50ml dosing pump and a timer (my APEX is used to turn on the pump for 4 min every 1/2 hour, it is not controlled by any switches, probes, or any other functions than time). RO/DI and 4 cups vinegar are added to the Brute with ~1.5 cups Kalk and mixed. I put on the lid and ensure the pump I take is secured above the settled Kalk at the bottom with a magnetic tube holder.
10" SRO-5000 skimmer with Avast neck Cleaner.
30 gallons chaeto refugium. Reacently replaced the fuge light with a powerful LED grow light and doubled the flow through it. The growth of cheato has increased so much, before I would harvest 1-2 months maybe. Now I am harvesting every 14-19 days because it completely fills the entire fuge.
This is two weeks growth:
Use BRS ROX .8 carbon in reactor once a month or so. No GFO as the chaeto completely handles the PO4 accumulation and in fact I have watched it fall consistently and yesterday test @ 0.01ppm via Hanna Checker ULR Phosphorus.
3 Each MarinePure blocks in my 100 gallon sump.
High flow (80x's display turn over)
Good light, 300-500 PAR, (Kessil AP700s, 2 each 80w T5 ATI Blue Plus)
Decent fish load and feed good food, PE mysis, RODs food, nori and some pellets. Few times a week I add Reef Chili and Reef Roids.
I built a RO/DI collection and salt mixing station that enables me to change water as quickly and easily as possible. ~100 gallons of RO/DI fill the station and a float valve automatically shuts it off when full. The pump, an Iwaki 40RLT both mixes and moves the water directly to my sump with a 3/4" hose with a CEPEX valve near the outlet gives me full control of flow. I need only open the lid and add two bags of IO then turn on pump. When the water is ready I just turn a valve and ready to fill sump. The display is drained via a Python hose to the sink. Never spill a drop. Never have to shut down the system, just a heater and powerhead in sump, fish never even notice something is happening. Altogether involves a total of 5-10 minutes of actual work. I love it.
I don't add additional additives other than some potassium nitrate once a month to maintain 2-5ppm NO3.
All I know for sure is that my tank has never looked better, corals happier, growth faster, colors better, or clearer water. Also cyano, dinos, diatoms, pest algae, and other nasties have virtually disappeared. This all directly linked to regular 100 gallons water changes with IO salt and 000 TDS RO/DI.
I wouldn't change anything and I feel like the system is doing well because I have eliminated potential problems and/or disaster. Not because I'm any kind of expert Reefer. I've just kept things simple and easy so that my water is the most consistent it can be. I would recommend to everyone that water changes are mandatory, but reserve the idea that "No water changes can be done" for those experts for which I am not.
I don't understand how the valve of water changes has been questioned. Certainly there may be fewer than 10-15 years ago but still the simplest effective and least risky method for maintaining water quality.