pH
8.4 isn't too, too bad as long as it's fairly consistent there (small/no swings) and doesn't go higher than that.
Adding Vinegar?
If you decide to add vinegar to the regime, you are right that more lime will be able to dissolve than without it. You'll have to control how much you dose.
Unfortunately there's no "lime" entry in the Reef Chemistry Calculator so you'll have to get a little creative to figure out what a correct dose is. One idea is to use the "saturated limewater" option in the Calculator to calculate your dose, then back-figure the amount of lime using an estimate of
2 grams of lime per 1 liter of saturated solution.
For example:
- Say your tank would fall from 8 to 7 dKH in a week without supplementation.
- The Reef Chemistry Calculator says you'd have to dose .87 gallons of saturated limewater to maintain levels for that week. That's about 3.3 liters of saturated limewater.
- 2 grams * 3.3 liters is about 6 grams of lime.
- So you'd dissolve 6 grams of lime into the prescribed amount of vinegar and you're all set.
You can use this same method to figure the "correct" weekly load for your reactor - just use the vinegar in your ATO vat to let the reactor do the mixing instead of mixing it directly with the lime.
Throttling ATO Flow
If you decide to throttle back your pump - "how" depends somewhat on your ATO so you'll have to decide what works. Might be worth a call to the ATO manufacturer for a tip on what your best practice will be.
One idea is simply to add a valve to the reactor output to slow the flow to something like a drip.
Another is if you can control the amount of time the ATO runs, just make it run for the shortest time possible.
Adding Air
Aerating your reservoir will not help If you suspected low aeration in the tank (along with the limewater dosing) as causing the elevated pH, then there's be a good reason to add air in the tank. If you run a skimmer and have decent water flow, its doubtful you'll have to worry about this.
Alkalinity Level
Anything up to 11-12 dKH is fine if you're running a normal tank - which mostly implies no carbon dosing and normal tank pH (which you appear to have), which you have - so I wouldn't worry. Just let it come down to where you want it on its own.
As far tweaking the reactor output, similar to the method above used to calculate the amount of lime to use with vinegar (for moderating pH), you can also just back-compute the amount of lime to load to control your dosing amount without using vinegar.
In the example used above under "Adding Vinegar" you would measure out the same 6 grams of lime, but instead of mixing with vinegar, you'd just load it into your lime reactor and then you should be set for the week. Verify with testing, of course.
Hope this makes sense!
-Matt