Warning: Use Vibrant at your own risk

Exactly.

I don't understand why some are trying to push this stuff as being more toxic than it actually is. What is the point in making people think they could be doing something illegal by pouring it down the drain?

lol

I don't understand why some are trying to push this stuff as being less toxic than it actually is. What is the point in making people think they could be doing something legal by pouring it down the drain?
 
Algaefix: dimethyliminoethylene dichloride, ethoxylate
Busan 77: Poly (oxy-1,2-ethanediyl(dimethylimino) 1,2-ethanediyl(dimethylimino)-1,2-ethanediyl dichloride

Are they the same?

They are the same or I would not have posted them as being the same.


The CAS # is a unique identifier for a chemical, even when there are lots of different names for it.

Algaefix claims it's cas number is : 31512-74-0


Busan 77 claims it's CAS # is: 31512-74-0

http://www.cimcool.com/sds/extract/pdf/PRS1014_BUSAN 77_BUCKMAN_050911.pdf
 
And - the issue here is 'concentration'. Obviously - assuming that 'Busan 77' is the same chemical thats in algaefix - there has to be a problem - since obviously -- when used 'fish' do not just die. I am not going through the EPA 'stuff' again - it was tedious enough last time - but - Obviously algaefix is not 'toxic to fish' - at the concentrations used.

Concentration is the issue for EVERY toxic molecule. A little is not toxic and may be needed, and a lot can be toxic.

NONE of these products are used at the concentration supplied. They are all diluted for use. Thus, the concentration in the bottle is of no relevance to the ultimate toxicity.
 
It's the same thing as algaefix accoridng to the tests, which means it's safe to pour down the drain.

First statement is supported by evidence. Second is an opinion of yours not supported by a single official statement.
 
If you follow the B77 dosing protocol for your pool laid out in that doc... (1oz per 1,000 US gal)... 1 oz =29.6 ml; 29.6 ml / 3,785 l = 0.0078 ml/l or 7.8 ppm; but the 'pure' stuff seems to be only 60% by weight, so maybe 4.7ppm...

Vibrant rec. dosing is 1ml/10gal of water, 0.026 ml/l, or 26ppm, but it's 4.5% soln by weight, so around 1.17ppm dosed to your tank (if you followed the directions).

So, if you had corals in your saltwater swimming pool, I think they might be in trouble.

Thank you for working through the calculations. to point out that the concentration in the bottle is not the important factor, its the concentration in use and in the drain/environment that matters.
 
who wants to debate chemistry and related warning labels?
I got a “A” in HS chemistry
PLUS 50yrs mixing koolaide, mixed drinks and house paint …
what you got? prolly some cheap ash pHD from Harvard or somewhere hah
:rolleyes:
 
Vibrant rec. dosing is 1ml/10gal of water, 0.026 ml/l, or 26ppm, but it's 4.5% soln by weight, so around 1.17ppm dosed to your tank (if you followed the directions).

Forgive me if someone has already posted this, but that concentration coupled with the EPA warning levels seems crazy bad to use Algaefix or Vibrant in a reef aquarium based on studies Algaefix actually submitted for approval:


"If you wish to be protective of aquarium organisms such as marine crustacea, further analyses of the concentration of Busan 77 in the water during treatment with AlgaeFix should be conducted to ascertain that it does not approach the levels shown to be toxic to marine invertebrate species in the submitted studies [Mysid, LC50=13ppm (95% confidence interval of 9.1 - 16ppm) NOEC <;7.8 ppm; Quahog clam, LC50 = 350 ppb (95% confidence interval of 0 - 71 Oppb), NOEC =230 ppbJ."
 
I wonder how many folks who dosed vibrant lost mollusks?

EDIT: And arthropods, and fish...

A number of folks lost clams. A least one Reef2Reef member lost a lot of clams.
 
I wonder how many folks who dosed vibrant lost mollusks?

EDIT: And arthropods, and fish...
Sorry but I’m going in…..
What are the damages then? Given the price of clams and the size and growth rate, I would be plenty mad if I lost one bcuz of irresponsible mislabeling or lack thereof… I already started a similar and the mods can kill (make it invisible) if nobody is asking and/or the discussion of liability and dead “pets” is off table
 
Thank you @taricha , @Randy Holmes-Farley , @jda and all the others who have devoted considerable time, effort and money to pursue this analysis, and for continuing that effort until we get to a conclusion.

I think @jeffww makes a very valid point.

Edit: Also I think you've completely misinterpreted Randy's and other's arguments. On principle, we as stewards of our hobby and the environment, should be concerned when we release any type of potentially harmful chemical. Whether or not Vibrant actually is harmful isn't important. Ethics doesn't begin when harm is done. What is important is that we continue to demand transparency in reporting so that everyone can make an informed decision. If not vibrant, there may be a day when we will have wished that irresponsible use of poorly understood chemicals was better policed by the hobby. ....

The title for this thread,

Warning: Use Vibrant at your own risk​

is entirely appropriate.

I am happy many have used and been satisfied with Vibrant and have not encountered any issues. That success does not mean this warning is not needed.

I personally had a terrible experience with freshwater AlgaeFix (which contains the same ingredient as Saltwater AlgaeFix per API SDS) two years ago. An hour after dosing, all of the fish in my 90 gallon african cichlid tank were under extreme duress. Even after a 60% water change, several fish died within the first 3 hours and more died over the next 3 days.

I recently purchased a bottle of Vibrant based on reviews in R2R and not knowing it was the same chemical as AlgaeFix. I was relieved when this thread and the earlier thread by @taricha appeared BEFORE I used Vibrant. Sure, if I had used it, perhaps no harm may have occurred. But the issue to me is very simple. The lack of transparency for this product was leading me down a path to make a decision I would not have made. Ironically, after buying the product, I sat on it for several weeks because I had not been able to determine what chemicals were in it.

Do not assume product reviews on vendors websites are always completely accurate. I wrote a review of my AlgaeFix experience and sent it to the on-line vendor and to API. API never responded. The on-line vendor sent me a dozen roses for my fish loss, but refused to publish my review or include my rating on their site, even after several back and forth emails asking why.

The AlgaeFix reviews on Amazon were a bit more revealing. While 68% responded favorably for AlgaeFix, many users reported problems similar to what I experienced. Sure, some will say all of us that lost fish just didn't know how to follow instructions. Nonetheless, transparency is lacking.

Whether it's Vibrant or many of the other products for which vendors do not disclose content (some of which @taricha has also studied) :

Warning: Use XXXXXXX at your own risk​


is entirely appropriate and I hope @Randy Holmes-Farley continues to point those products out in the future.
 
Curious if any of contacted the EPA, FDA or CIA (joke) about these concerns. No clue who exactly should be contacted but at this point I think UWC has been given ample time to have their lawyers read and I expect they might just claim there's more to read as these pages keep growing. Know this. Their lawyers likely not worried about the price of oil rising. They can now easily afford it.
 
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Curious if any of contacted the EPA, FDA or CIA (joke) about these concerns. No clue who exactly should be contacted but at this point I think UWC has been given ample time to have their lawyers read and I expect they might just claim there's more to read as these pages keep growing. Know this. Their lawyers likely not worried about the price oil rising. They can now easily afford it.
I still firmly believe UWC is doing nothing at all.
 

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