You have to open the primary valve slowly and only to the point that the water level stays at the height of the secondary. That may mean that the valve is only partly open.
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I have another idea for you to try. Pull the U bend off the secondary and raise the remaining stand pipe so it is about 1/2” lower than the emergency. Then slowly open the primary valve until there is just a trickle going down the secondary but nothing down the emergency.
The bubbles you are seeing is because there’s a lot of water going down the secondary.
If the bubbles are coming out of the main siphon and the air isn't coming from the overflow then i'm leaning towards a venturi somewhere. Make sure your connections at the sump are all tight. Mine used a slip to male into a female to slip to create the bulkhead and the threads weren't tight and air was being sucked in through there creating a similar sound.
I have another idea for you to try. Pull the U bend off the secondary and raise the remaining stand pipe so it is about 1/2” lower than the emergency. Then slowly open the primary valve until there is just a trickle going down the secondary but nothing down the emergency.
The bubbles you are seeing is because there’s a lot of water going down the secondary.
Having a rolling wave in a reef tank is mostly overrated anyhow. Move the vortech down and run them on reef rest mode with one anti sync to the other. That’ll give you a stable water surface and better overflow performance.

